Combination with catalyzed Fe(0)-carbon microelectrolysis and activated carbon adsorption for advanced reclaimed water treatment: simultaneous nitrate and biorefractory organics removal

A process combining catalyzed Fe(0)-carbon microelectrolysis (IC-ME) with activated carbon (AC) adsorption was developed for advanced reclaimed water treatment. Simultaneous nitrate reduction and chemical oxygen demand (COD) removal were achieved, and the effects of composite catalyst (CC) addition, AC addition, and initial pH were investigated. The reaction kinetics and reaction mechanisms were calculated and analyzed. The results showed that CC addition could enhance the reduction rate of nitrate and effectively inhibit the production of ammonia. Moreover, AC addition increased the adsorption capacity of biorefractory organic compounds (BROs) and enhanced the degradation of BRO. The reduction of NO₃^?–N at different pH values was consistently greater than 96.9%, and NH₄⁺–N was suppressed by high pH. The presence of CC ensured the reaction rate of IC-ME at high pH. The reaction kinetics orders and constants were calculated. Catalyzed iron scrap (IS)-AC showed much better nitrate reduction and BRO degradation performances than IS-AC and AC. The IC-ME showed great potential for application to nitrate and BRO reduction in reclaimed water.

     

A remote sensing tool for near real-time monitoring of harmful algal blooms and turbidity in reservoirs

Harmful algal blooms (HABs) diminish the utility of reservoirs for drinking water supply, irrigation, recreation, and ecosystem service provision. HABs decrease water quality and are a significant health concern in surface water bodies. Near real-time monitoring of HABs in reservoirs and small water bodies is essential to understand the dynamics of turbidity and HAB formation. This study uses satellite imagery to remotely sense chlorophyll-a concentrations (chl-a), phycocyanin concentrations, and turbidity in two reservoirs, the Grand Lake O′ the Cherokees and Hudson Reservoir, OK, USA, to develop a tool for near real-time monitoring of HABs. Landsat-8 and Sentinel-2 imagery from 2013 to 2017 and from 2015 to 2020 were used to train and test three different models that include multiple regression, support vector regression (SVR), and random forest regression (RFR). Performance was assessed by comparing the three models to estimate chl-a, phycocyanin, and turbidity. The results showed that RFR achieved the best performance, with R² values of 0.75, 0.82, and 0.79 for chl-a, turbidity, and phycocyanin, while multiple regression had R² values of 0.29, 0.51, and 0.46 and SVR had R² values of 0.58, 0.62, and 0.61 on the testing datasets, respectively. This paper examines the potential of the developed open-source satellite remote sensing tool for monitoring reservoirs in Oklahoma to assess spatial and temporal variations in surface water quality.     

Study of the performance of a coolant mixed with an Al2O3/SiC nanomaterial in an engine radiator

One of the important components of a car to control the temperature of a car's engine is the radiator. To increase the heat absorption capacity of the coolant/fluid used in the radiator with minimum pumping power, innovative fluids called nanofluids have become the main area of research these days. Therefore, with the development of new technologies in the field of “nano-materials” and “nano-fluids,” the physical and chemical properties of coolant/fluid can be improved which in turn improves the radiator and engine efficiency, and reduces radiator weight and size. In this article, the heat transfer by forced convection in nanofluids based on Al₂O₃ and SiC was studied experimentally and compared to that of base fluid in an automotive radiator. The nanofluid is mixed with ethylene glycol and the fluid is prepared by the sonication method. The nanofluids were prepared by varying the nanomaterials and the amounts of nanomaterials in the base fluid and their heat transfer performance in the radiator was analyzed using ANSYS FLUENT software. Approximately 15% and 12% increase in radiator efficiency by using Al₂O₃ mixed nanofluid and SiC mixed nanofluid, respectively.     

Changes in electrical generator cooling systems: Are they cost-effective sources of water now and under climate change?

In the United States, thermal power plant electrical generators (EGs) are large water diverters and consumptive users who need water for cooling. Retrofitting existing cooling systems to dry cooling and building new facilities with dry cooling can save water and reduce EG's vulnerability to drought. However, this can be an expensive source of water. We estimate that the cost of water saved by retrofitting cooling in existing EGs ranges from $0.04/m³ to $18/m³ depending on facility characteristics. Also water savings from building new EGs with dry cooling ranges in cost per unit water from $1.29/m³ to $2.24/m³. We compare costs with that for water development projects identified in the Texas State Water Plan. We find the water cost from converting to dry cooling is lower than many of the water development possibilities. We then estimate the impact of climate change on the cost of water saved, finding climate change can increase EG water use by up to 9.3% and lower the costs of water saved. Generally, it appears that water planners might consider cooling alterations as a cost competitive water development alternative whose cost would be further decreased by climate change.     

The nexus across water,energy and food (WEF): Learning from research,building on evidence,strengthening practice

While water-energy-food (WEF) Nexus is one of the most important, and widely investigated, environmental topics of our time, previous stock taking efforts possess notable limitations, namely (i) their focus is restricted to research articles, and (ii) there is less focus on nexus permutations that begin with energy and food. This paper assembled more than 900 documents and systematically categorized them according to more than 10 key parameters (e.g. scale, methods, limitations), to characterize approaches, achieved outcomes and presence of variables likely to support on-the-ground change. Our results reveal that WEF Nexus activities are often driven by the water sector, undertaken at global and national scale and authored by experts from diverse backgrounds. Among the utilized methods, modelling and review (i.e. systematic) are the most common. While climate change and governance are routinely considered in WEF Nexus documents, gender, stakeholders and capacity are not. These findings highlight areas for improvement in the design of WEF Nexus initiatives.     

Air Quality Modeling Using the PSO-SVM-Based Approach,MLP Neural Network,and M5 Model Tree in the Metropolitan Area of Oviedo (Northern Spain)

The main aim of this study was to construct several regression models of air quality using techniques based on the statistical learning, in the metropolitan area of Oviedo, in northern Spain. In this research, a hybrid particle swarm optimization-based evolutionary support vector regression is implemented to predict the air quality from the experimental dataset (specifically, nitrogen oxides, carbon monoxide, sulfur dioxide, ozone, and dust) collected from 2013 to 2015 in the metropolitan area of Oviedo. Furthermore, a multilayer perceptron network (MLP) and the M5 model tree were also fitted to the experimental dataset for comparison purposes. Finally, the predicted results show that the hybrid proposed model is more robust than the MLP and M5 model tree prediction methods in terms of statistical estimators and testing performances.     

Sb release characteristics of the solid waste produced in antimony mining smelting process

Sb release characteristics of blast furnace slag, mining waste rock and tailing sand were investigated in static immersion and dynamic leaching test. These three kinds of waste samples were collected from the antimony mine in Lengshuijiang, China, produced in mining smelting process. Effects of solid/liquid ratio, sample size and pH of leaching solution on Sb release characteristics were inspected based on the analysis of scanning electron microscope, pH and EC of leachate. The optimal parameters for Sb leaching of each sample were analyzed. For blast furnace slag and mining waste rock, Sb release contents increased along with the decline of solid/liquid ratio. The maximum accumulative release contents were 42.13, 34.26 mg/kg at the solid/liquid ratio of 1:20. While Sb release content for tailing sand decreased first and then increased with the reduction of solid/liquid ratio. When the solid/liquid ratio was 1:5, the accumulative Sb release content reached the most (24.30 mg/kg). Sb release content of mining waste rock increased with the drop of leaching solution pH, with the highest accumulative release content of 26.01 mg/kg at pH 2.0. Sb release contents of blast furnace slag and tailing sand showed positive correlation with the variation of leaching solution pH. The maximum accumulative release contents of these two samples were 215.91 and 147.83 mg/kg, respectively, when leaching solution pH was 7.0. In summary, Sb release capacity of the three samples in descending order was tailing sand, blast furnace slag and mining waste rock. pH and EC of the leachate in dynamic test varied independently with the initial pH of leaching solution while showing close relationship with mineral hydrolysis in the waste.     

Are older drivers’ driving patterns during an on-road driving task representative of their real-world driving patterns?

Abstract

Objective: The current study investigated whether older drivers’ driving patterns during a customized on-road driving task were representative of their real-world driving patterns.

Methods: Two hundred and eight participants (male: 68.80%; mean age?=?81.52 years, SD?=?3.37 years, range?=?76.00–96.00 years) completed a customized on-road driving task that commenced from their home and was conducted in their own vehicle. Participants’ real-world driving patterns for the preceding 4-month period were also collected via an in-car recording device (ICRD) that was installed in each participant’s vehicle.

Results: During the 4-month period prior to completing the on-road driving task, participants’ median real-world driving trip distance was 2.66?km (interquartile range [IQR]?=?1.14–5.79?km) and their median on-road driving task trip distance was 4.41?km (IQR?=?2.83–6.35?km). Most participants’ on-road driving task trip distances were classified as representative of their real-world driving trip distances (95.2%, n?=?198).

Conclusions: These findings suggest that most older drivers were able to devise a driving route that was representative of their real-world driving trip distance. Future research will examine whether additional aspects of the on-road driving task (e.g., average speed, proportion of trips in different speed zones) are representative of participants’ real-world driving patterns.     

Socio-environmental consideration of phosphorus flows in the urban sanitation chain of contrasting cities

Understanding how cities can transform organic waste into a valuable resource is critical to urban sustainability. The capture and recycling of phosphorus (P), and other essential nutrients, from human excreta is particularly important as an alternative organic fertilizer source for agriculture. However, the complex set of socio-environmental factors influencing urban human excreta management is not yet sufficiently integrated into sustainable P research. Here, we synthesize information about the pathways P can take through urban sanitation systems along with barriers and facilitators to P recycling across cities. We examine five case study cities by using a sanitation chains approach: Accra, Ghana; Buenos Aires, Argentina; Beijing, China; Baltimore, USA; and London, England. Our cross-city comparison shows that London and Baltimore recycle a larger percentage of P from human excreta back to agricultural lands than other cities, and that there is a large diversity in socio-environmental factors that affect the patterns of recycling observed across cities. Our research highlights conditions that may be “necessary but not sufficient” for P recycling, including access to capital resources. Path dependencies of large sanitation infrastructure investments in the Global North contrast with rapidly urbanizing cities in the Global South, which present opportunities for alternative sanitation development pathways. Understanding such city-specific social and environmental barriers to P recycling options could help address multiple interacting societal objectives related to sanitation and provide options for satisfying global agricultural nutrient demand.